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101.
T.?A.?Prokof’evEmail author B.?A.?Polezhaev A.?V.?Kovalenko 《Journal of Applied Spectroscopy》2005,72(6):865-871
The mechanisms of photoluminescence excitation of Mn2+ ions in ZnS crystals have been investigated on the basis of complex analysis of the temperature dependences of the photoluminescence
and photoluminescence-excitation spectra of ZnS:Mn crystals. The activation energy of a manganese luminescence center was
estimated at Ea = 0.17 ± 0.05 eV. It is shown that Ea represents an energy band with a width ΔEa = 0.1 eV, within which a manganese luminescence center can experience radiationless recombination.
__________
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 72, No. 6, pp. 788–793, November–December, 2005. 相似文献
102.
We describe the construction and operation of a variable temperature (VT) system for a high field fast magic angle spinning (MAS) probe. The probe is used in NMR investigations of biological macromolecules, where stable setting and continuous measurement of the temperature over periods of several days are required in order to prevent sample overheating and degradation. The VT system described is used at and below room temperature. A vortex tube is used to provide cooling in the temperature range of -20 to 20 degrees C, while a liquid nitrogen-cooled heat exchanger is used below -20 degrees C. Using this arrangement, the lowest temperature that is practically achievable is -140 degrees C. Measurement of the air temperature near the spinning rotor is accomplished using a fiber optic thermometer that utilizes the temperature dependence of the absorption edge of GaAs. The absorption edge of GaAs also has a magnetic field dependence that we have measured and corrected for. This dependence was calibrated at several field strengths using the well-known temperature dependence of the (1)H chemical shift difference of the protons in methanol. 相似文献
103.
Mojia Huang 《Journal of the mechanics and physics of solids》2004,52(8):1827-1853
Herein we obtain a formula for the effective elastic stiffness tensor Ceff of an orthorhombic aggregate of cubic crystallites by the perturbation method. The effective elastic stiffness tensor of the polycrystal gives the relationship between volume average stress and volume average strain. Under Voigt's model, Reuss’ model and Man's theory, the elastic constitutive relation accounts for the effect of the orientation distribution function (ODF) up to terms linear in the texture coefficients. However, the formula derived in this paper delineates the effect of crystallographic texture on elastic response and shows quadratic texture dependence. The formula is very simple. We also consider the influence of grain shape to elastic constitutive relations of polycrystals. Some examples are given to compare computational results of the formula with those given by Voigt's model, Reuss's model, the finite element method, and the self-consistent method. In Section 3, we also present an expression of the perturbation displacement field, in which Green's function for an orthorhombic aggregate of cubic crystallites is included. 相似文献
104.
Intermolecular photoinduced electron transfer (PET) in a gas phase was studied using carbazole vapor fluorescence quenching by halomethanes (CHCl3, CH2Br2, CCl4, CHBr3). The fluorescence quenching rate constants k
q changing from 2.3·105 sec–1·torr–1 in mixtures with CHCl3 to 4.6·106 sec–1·torr–1 in mixtures with CHBr3 at a constant temperature of 403 K were estimated. The dependence of the carbazole fluorescence decay rates in the presence of halomethanes on the free energy change G during transfer of the electron from carbazole to halomethanes is considered. It is suggested to take into account the influence of the vibrational energy of the carbazole molecule E
vib and its temperature changes in estimation of the G values. The differences between PET in the gas and liquid phases were analyzed. It is found that for mixtures with CCl4 and CHBr3 the negative temperature dependence of k
q is observed, when the decay rates and efficiencies of the intermolecular PET decreased with temperature increase in the range 403–573 K, i.e. these mixtures the electron transfer is not a barrier-restricted process. 相似文献
105.
David Eisenbud Craig Huneke Bernd Ulrich 《Proceedings of the American Mathematical Society》2003,131(3):701-708
In this paper we show that the Rees algebra can be made into a functor on modules over a ring in a way that extends its classical definition for ideals. The Rees algebra of a module may be computed in terms of a ``maximal' map from to a free module as the image of the map induced by on symmetric algebras. We show that the analytic spread and reductions of can be determined from any embedding of into a free module, and in characteristic 0--but not in positive characteristic!--the Rees algebra itself can be computed from any such embedding.
106.
Baha-Eldin Khaledi Subhash Kochar 《Annals of the Institute of Statistical Mathematics》2001,53(3):620-630
Consider a multivariate mixture model where the random variables X
1, ..., X
n
given (1, ...,
n
), are conditionally independent. Conditions are obtained under which different kinds of positive dependence hold among X
i
's. The results obtained are applied to a variety of problems including the concomitants of order statistics and of record values; and to frailty models. 相似文献
107.
108.
We study rate of convergence in the strong law of large numbers for finite and infinite variance time series in both contexts of weak and strong dependence. 相似文献
109.
Beghin Luisa Knopova Viktoria P. Leonenko Nikolai N. Orsingher Enzo 《Journal of statistical physics》2000,99(3-4):769-781
We analyze the asymptotic behavior of the rescaled solution to the linear Korteweg–de Vries equation when the initial conditions are supposed to be random and weakly dependent. By means of the method of moments we prove the Gaussianity of the limiting process and we present its correlation function. The same technique is applied to the analysis of another third-order heat-type equation. 相似文献
110.
Deutsch and Hayden have proposed an alternative formulation of quantum mechanics which is completely local. We argue that
their proposal must be understood as having a form of ‘gauge freedom’ according to which mathematically distinct states are
physically equivalent. Once this gauge freedom is taken into account, their formulation is no longer local.
相似文献